铑
CAS号：14694-95-2
品名：氯化三(三苯基膦)合铑(I)Chlorotris(triphenylphosphine)rhodium(I)
中文别名：威尔金森催化剂;三(三苯基膦)氯化铑;铑膦;三苯基膦氯铑(I);三(三苯基膦)氯化铑(I);三(三苯磷)铑氯化物;三(三苯基膦)合铑氯;
英文别名：Wilkinson'scatalyst;Tris(triphenylphosphine)chlororhodium;(SP-4)chloridotris(triphenylphosphane)\r\nrhodium;Rhodium(I)tris(triphenylphosphine)chloride;Tris(triphenylphosphine)rhodium(I)chloride;RhCl(PPh3)3;
分子式：C54H45ClP3Rh
分子量：925.215
精确质量：924.148
Psa：40.77
BRN号：4581440
EINECS号：238-744-5
MDL号：MFCD00010016
PubChem号：24889752
外观与性状：洋红晶体
密度：
沸点：&>170°C
熔点：245-250°C (dec.)
闪点：181.7ºC
稳定性：Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件：2-8ºC
安全说明：S22-S24/25-S37/39-S28A-S26-S15
危险类别码：R36/38
WGK Germany：1
海关编码：2942000000
包装等级：I; II; III
危险品标志：Xi
简介：Wilkinson'scatalystisthecommonnameforchlorotris(triphenylphosphine)rhodium(I),acoordinationcompoundwiththeformulaRhCl(PPh3)3(Ph=phenyl).ItisnamedafterthechemistandNobelLaureate,SirGeoffreyWilkinsonwhopopularizeditsuse.Wilkinson’scatalystisahomogeneousorganometalliccatalyst,RhCl(PPh3)3,whichcatalyzesthehydrogenationofolefins.Catalyticprocessescanbecategorizedintotwogroups:1)homogeneouscatalysiswhichisaprocesswherethecatalystsandreactantsremaininthesamephase;and2)heterogeneouscatalysiswhichdefinesaswherethereactantsandcatalystsareindifferentphases.ThecatalyticdiscoverywasmadeindependentlybyWilkinsonandCoffeyin1964.Wilkinsoncompletelyexploredthescope,selectivity,andmechanismofthecomplexwhichcatalyzesthehydrogenationofolefins.Thiscompoundisnowcommonlyreferredtoas“Wilkinson’scatalyst\".Citeerror:A
用途：1.石蜡加氢催化剂;
