CAS号:80049-61-2
品名:三(乙腈基)环戊二烯六氟磷酸钌Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate
中文别名:三(乙腈基)环戊二烯基钌六氟磷酸;
英文别名:Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate
分子式:C11H14F6N3PRu
分子量:434.283
精确质量:434.987
Psa:84.96
MDL号:MFCD02684569
密度:
储存条件:Refrigerator (+4ºC)
危险品标志:Xi
简介:Tris(acetonitrile)cyclopentadienylrutheniumhexafluorophosphateisanorganorutheniumcompoundwiththeformula[(C5H5)Ru(NCCH3)3]PF6,abbreviated[CpRu(NCMe)3]PF6.Itisayellow-brownsolidthatissolubleinpolarorganicsolvents.Thecompoundisasaltconsistingofthehexafluorophosphateanionandthecation[CpRu(NCMe)3]+.Incoordinationchemistry,itisusedasasourceofRuCp+forfurtherderivitization.Inorganicsynthesis,itisahomogeneouscatalyst.ItenablesC-Cbondformationandpromotescycloadditions.Thecyclopentadienylligand(Cp)isbondedinanη5mannertotheRu(II)center.
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