CAS号:3238-40-2
品名:2,5-呋喃二甲酸furan-2,5-dicarboxylicacid
中文别名:2,5-呋喃二羧酸;呋喃-2,5二羧酸;
英文别名:Dehydroschleimsaeure;Dehydromucate;Dehydromucicacid;2,5-furandicarboxylate;2,5-dicarboxyfuran;furan-2,5-dicarbonsaeure;Furan-2,5-dicarboxylicacid;2,5-FurandicarboxylicAcid;2,5-Furandicarboxylicacid;
分子式:C6H4O5
分子量:156.093
精确质量:156.006
Psa:87.74
MDL号:MFCD00016582
密度:0.936g/mLat 25°C(lit.)
沸点:56°C1mm Hg(lit.)
闪点:168°F
折射率:n20/D 1.461(lit.)
安全说明:S26-S36/37/39
危险类别码:R36/37/38
海关编码:2932190090
危险品标志:Xi
信号词:Warning
危险性防范说明:P280; P305 + P351 + P338; P337 + P313
危险标志:GHS07
危险性描述:H319
简介:2,5-Furandicarboxylicacid(FDCA),alsoknownasdehydromucicacid,isanoxidizedfuranderivative.ThisorganiccompoundwasfirstobtainedbyFittigandHeinzelmannin1876.ThefirstreviewbyHenryHillwasalreadypublishedin1901.FDCAhasalsobeendetectedinhumanurine.Ahealthyhumanproduces3–5mg/day.Numerousstudieswereundertakentoestablishthemetabolismofthiscompoundandtodeterminethequantity,whichisproduceddependingonthehealthinessofthehuman.ItwasdemonstratedthattheindividualquantityofproducedFDCAincreasedaftertheinjectionoffructose.FDCAwasalsodetectedinbloodplasma.FDCAwasmorethan125yearslateridentifiedbytheUSDepartmentofEnergyasoneof12prioritychemicalsforestablishingthe“green”chemistryindustryofthefuture.Furan-2,5-dicarboxylicacid(FDCA)hasbeensuggestedasanimportantrenewablebuildingblockbecauseitcansubstituteforterephthalicacid(PTA)intheproductionofpolyestersandothercurrentpolymerscontaininganaromaticmoiety.InMarch2016,AvantiumandBASFannouncedthattheyintendtoestablishofajointventuretoerecta50,000t/aplantfortheproductionofFDCAbasedonfructoseatBASF'sVerbund-siteinAntwerp,Belgium.
呋喃